Bound Volume Number
Volume III
Degree Type
Honors Capstone Project
Date of Submission
Spring 5-2016
Capstone Advisor
Daniel Clark
Capstone Major
Chemistry
Capstone College
Arts and Science
Audio/Visual Component
no
Keywords
Synthesis, organometallic chemistry, polymer chemistry
Capstone Prize Winner
no
Won Capstone Funding
no
Honors Categories
Sciences and Engineering
Subject Categories
Chemistry
Abstract
Various propargyl alcohols were synthesized via Grignard reactions. These alkynic alcohols are tethered with dimethyl and biphenyl silicon tethers. These terminal alkyne substrates are reacted with RuHCl(CO)(H2IMes)(PPh3) as a catalyst under high pressure (80 psi) ethylene atmosphere to afford the 5-exo-dig trans-silylvinylation product in poor yield. Internal alkyne substrates are found to be much more efficiently transformed into the silylvinylation product, favoring one cycloisomer product over the other.
Recommended Citation
Beaton Jr., Alec, "Ruthenium Hydride Catalyzed Silylvinylation of Terminal and Internal Alkynes and Synthesis of Poly(trimethylenecarbonate) and Poly(dimethylacrylamide) Block Copolymer" (2016). Renée Crown University Honors Thesis Projects - All. 968.
https://surface.syr.edu/honors_capstone/968
Creative Commons License
This work is licensed under a Creative Commons Attribution 3.0 License.