Document Type

Article

Date

9-1978

Keywords

Chemistry

Disciplines

Chemistry

Description/Abstract

A model is proposed for the two-particle distribution functions for the surface region of a system composed of two oppositely charged species with identical hard sphere repulsions. The distribution functions are formed from those for the bulk fluid by incorporating a cutoff corresponding to the surface and a multiplying factor defined so as to guarantee electroneutrality while maintaining the proper symmetry. Various methods for doing this are discussed. Good agreement is obtained for surface tension and surface energy. Density oscillations are predicted.

Additional Information

Reprinted with permission from Goodisman, J., & Pastor, R. W. (1978). A model for the surface of a molten salt. Journal of Physical Chemistry, 82(19), 2078-2081. Copyright 1978 American Chemical Society

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local input

Creative Commons License

Creative Commons Attribution 3.0 License
This work is licensed under a Creative Commons Attribution 3.0 License.

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Chemistry Commons

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