Title

The Synthesis of Some New Alkyland Arylaminoalkyl Aryl Sulfides

Date of Award

1958

Degree Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

Department

Chemistry

Advisor(s)

Gerald F. Grillot

Keywords

Aromatic amines, Benzenethiols, Formadehyde

Subject Categories

Chemistry

Abstract

The purposes of this investigation are to determine whether aromatic amines, primary and secondary, will condense with benzenethiols and formaldehyde in the raio of one part thiol: one part formaldehyde: one part amine to form the simple N-arylaminomethyl aryl sulfides in the case of the primary amines, and N-alkyl-N-arylaminomethyl aryl sulfides in the case of the secondary amines, or whether N-arylaminomethylbenzenethiols are formed; to determind whether the reaction with primary aromatic amines can be controlled so as to form 1, 3, 5-triaryl-1,5-dithia-3-azapentanes [bis -(arylthiomethyl) anilines],

Ar-S,CH2-N-Ch2-S-Ar

'

Ar

when the ratio of thiol: formaldehyde: amine is 2:2:1.

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