Title

The Photochemical Rearrangements of 4-Cyclopropyl-4-Phenylcyclohexenone and the Corresponding Dienone

Date of Award

1972

Degree Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

Department

Chemistry

Advisor(s)

Roger C. Hahn

Keywords

4, 4-Disubstitutedcyclonhexenones, Cyclohexadienones

Subject Categories

Chemistry

Abstract

4, 4-Disubstitutedcyclonhexenones (1) and cyclohexadienones (2) have long been known to arrange photochemically to bicyclone [3.1.0] hexanones (3) and bicyclo[3.1.0]-hex-3-ene-2-ones (4), respectively. Because of the structural similarity of these products, both the cyclonhexenone and dienone photoreactions have been studied extensively and their reactivities compared and contrasted by many investigators. Detailed reviews of both enone 1-3 and dienone photochemistry 3,4 have emphasized the generality of these reactions.

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